• An NQR study of inclusion compounds formed between small chlorine-containing molecules and bis(N-alkylimidazolidine-2-thione)Cu(I) halide complexes
    Y.-N. Zhao, S. Ramaprabhu and E.A.C. Lucken
    Zeitschrift für Naturforschung A, 51 (1996), p677-685
    unige:2824
Bis(N-methylimidazolidinethi-2-one)copper(I) chloride has been synthesized and its crystal structure determined. X-Irradiation of a single crystal of this compound leads to the formation of a CuII complex which was studied by EPR: it was shown that this species results from the addition of a radiogenic Cl atom on the CuI precursor. The structural changes induced by this reaction are revealed by the g-tensor and by the hyperfine tensors of one copper and two chlorine nuclei. The structure of this S2Cl2Cu type complex was compared with other sulfur- or chlorine-containing CuII complexes.
  • N-alkylimidazolidine-2-thione dihalogenocuprate anions : preparation, structure and nuclear quadrupole resonance spectra
    S. Ramaprabhu, N. Amstutz, E.A.C. Lucken and G. Bernardinelli
    Journal of Chemical Research, Synopses, (1994), p368-369

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